| tert-Butyl 5-bromo-2-(methylthio)-6-oxopyrimidine-1-acetate |
| tert-Butyl [5-bromo-2-(methylthio)-6-oxopyrimidin-1(6H)-yl]acetate |
| Formula: |
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Purity: |
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| MW: |
335.22 |
CAS#: |
C11H15BrN2O3S |
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| Cat# |
| B2802M500 |
| B2802G1 |
| B2802G5 |
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InChI: 1/C11H15BrN2O3S/c1-11(2,3)17-8(15)6-14-9(16)7(12)5-13-10(14)18-4/h5H,6H2,1-4H3 |
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| The pyrimidine scaffold tert-butyl 5-bromo-2-(methylthio)-6-oxopyrimidine-1-acetate couples selectively at the bromine atom without copper. Simply adding CuTC switches the selectivity to the thioether: Kusturin, C.; Liebeskind, L. S.; Rahman, H.; Sample, K.; Schweitzer, B.; Srogl, J.; Neumann, W. L. Org. Lett.; 2003; 5(23); 4349. |
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| ph 919.875.9277 fx 919.875.9601 |
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